Molecular coordination inheritance of single Co atom catalysts for two-electron oxygen reduction reaction

Abstract

Electrosynthesis of hydrogen peroxide (H₂O₂) through the two-electron oxygen reduction reaction (2e-ORR) is environmentally friendly and sustainable. Transition-metal single-atom catalysts (SACs) have gained attention for this application due to their low cost, high atom utilization, adjustable coordination, and geometric isolation of active metal sites. Although various synthetic methods of SACs have been reported, the specific mechanism of the formation of active sites is still less studied. Herein, we presented the molecular coordination inheritance strategy for synthesizing 2e-ORR SACs with well-defined coordination environments and investigated the formation mechanism of the active sites. We select precursors including [Co(II)Salen], CoPc, Co(acac)₂ to achieve specific configurations (Co–N₂O₂, Co–N₄, Co–O₄). Our results indicate that the precursors undergo decomposition and are partially embedded in the carbon substrate at lower temperatures, facilitating the inheritance of the desired configurations. As the temperature increases, the inherited configurations will rearrange, forming dual-atom structures and metal particles gradually. Among the Co–N₂O₂, Co–N₄, and Co–O₄ catalysts, the Co–N₂O₂ catalyst demonstrates the highest 2e-ORR selectivity. This work reveals the mechanism of regulating SAC's active site structure by the molecular coordination inheritance strategy, which may provide new insights for further research on the precise regulation and formation mechanism of SAC's active site.