Synthesis of N-trifluoromethylsulfilimines via trifluoromethyl nitrene and their synthetic potential

Norbert Baris; Martin Dračínský; Luca Julianna Tóth; Blanka Klepetářová; Petr Beier

doi:10.1039/D5QO00873E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Synthesis of N-trifluoromethylsulfilimines via trifluoromethyl nitrene and their synthetic potential†

Norbert Baris,^ab Martin Dračínský,

^a Luca Julianna Tóth,^ab Blanka Klepetářová^a and Petr Beier

*^a

Author affiliations

* Corresponding authors

^a Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo náměstí 2, 166 00 Prague, Czechia
E-mail: beier@uochb.cas.cz

^b Department of Organic Chemistry, Faculty of Science, Charles University, Hlavova 2030/8, 128 43 Prague, Czechia

Abstract

Trifluoromethyl nitrene generated photocatalytically from azidotrifluoromethane was added to sulfides to afford new N-trifluoromethylsulfilimines. Their methylation yielded N-methyl-N trifluoromethyl sulfonium salts and oxidation provided N-trifluoromethyl sulfoximines.

Download options Please wait...

Supplementary files

Transparent peer review

To support increased transparency, we offer authors the option to publish the peer review history alongside their article.

View this article’s peer review history

Article information

DOI: https://doi.org/10.1039/D5QO00873E
Article type: Research Article
Submitted: 10 Jun 2025
Accepted: 24 Jun 2025
First published: 25 Jun 2025
This article is Open Access

Download Citation

Org. Chem. Front., 2025, Advance Article

Permissions

Request permissions

Synthesis of N-trifluoromethylsulfilimines via trifluoromethyl nitrene and their synthetic potential

N. Baris, M. Dračínský, L. J. Tóth, B. Klepetářová and P. Beier, Org. Chem. Front., 2025, Advance Article , DOI: 10.1039/D5QO00873E

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Organic Chemistry Frontiers

Synthesis of N-trifluoromethylsulfilimines via trifluoromethyl nitrene and their synthetic potential†

Abstract

Supplementary files

Transparent peer review

Article information

Download Citation

Permissions

Synthesis of N-trifluoromethylsulfilimines via trifluoromethyl nitrene and their synthetic potential

Social activity

Search articles by author

Spotlight

Advertisements