Issue 1, 2001
From the journal:

Chemical Communications

Carbon–carbon bond forming reactions of N-bound transition metal α-cyanocarbanions: a mechanistic probe for catalytic Michael reactions of nitrilesElectronic supplementary information (ESI) available. Experimental section. See http://www.rsc.org/suppdata/cc/b0/b007517p/Dedicated to Professor J. F. Normant on the occasion of his 65th birthday.

Takeshi Naota,*a   Akio Tannnaa  and  Shun-Ichi Murahashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka, Japan.
E-mail: naota@chem.es.osaka-u.ac.jp

Abstract

N-Bound α-cyanocarbanion complexes Ru+Cp(NCCH−R1)(PPh3) 2 1 react with electron deficient olefins to afford the conjugate adduct Ru+Cp(NCC−R1CHR2CR3 R4)(PPh3)2 2, kinetic studies of which revealed that complex 1-catalyzed Michael reactions of nitriles proceed via transformation of 1 to 2 and subsequent ligand exchange with nitriles.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B007517P
Article type
Communication
Submitted
18 Sep 2000
Accepted
09 Nov 2000
First published
14 Dec 2000

Chem. Commun., 2001, 63-64

Permissions

Request permissions

Carbon–carbon bond forming reactions of N-bound transition metal α-cyanocarbanions: a mechanistic probe for catalytic Michael reactions of nitriles

T. Naota, A. Tannna and S. Murahashi, Chem. Commun., 2001, 63 DOI: 10.1039/B007517P

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements