Issue 1, 2001
From the journal:

Chemical Communications

1J(199Hg199H g) values of up to 284 kHz in complexes of [Hg–Hg]2+ with crown ethers: the largest indirect coupling constants

Richard Malleier,a   Holger Kopacka,a   Walter Schuh,a   Klaus Wursta  and  Paul Peringer*a  

* Corresponding authors

a Institut für Allgemeine, Anorganische und Theoretische Chemie, Universität Innsbruck, Innrain 52a, Innsbruck, Austria.
E-mail: paul.peringer@uibk.ac.at

Abstract

The values of the 1J(199Hg199Hg) coupling constant in solution of the asymmetric dimercury(2+) complexes with the stoichiometries Hg22+/18-crown-6 and Hg22+/18-crown-6/15-crown-5 are 220300 and 284100 Hz, respectively, representing the largest scalar couplings measured.

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Article information

DOI
https://doi.org/10.1039/B007581G
Article type
Communication
Submitted
18 Sep 2000
Accepted
14 Nov 2000
First published
19 Dec 2000

Chem. Commun., 2001, 51-52

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1 J(199Hg199H g) values of up to 284 kHz in complexes of [Hg–Hg]2+ with crown ethers: the largest indirect coupling constants

R. Malleier, H. Kopacka, W. Schuh, K. Wurst and P. Peringer, Chem. Commun., 2001, 51 DOI: 10.1039/B007581G

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