The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)-cyclopentan e/[PdCl(C3H5)]2 system catalyses allylic amination in good yields with a very high substrate/catalyst ratio; a turnover number of 680 000 and a turnover frequency of 8125 h−1 can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.
Dramatic acceleration of the catalytic process of the amination of allyl acetates in the presence of a tetraphosphine/palladium system
M. Feuerstein, D. Laurenti, H. Doucet and M. Santelli, Chem. Commun., 2001, 43 DOI: 10.1039/B007860N
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