Issue 1, 2003
From the journal:

Chemical Communications

Solvatochromic response imposed by environmental changes in matrix/chromophore entities: luminescent cyclometalated platinum(ii) complex in Nafion and silica materials†

Chi-Ming Che,*a   Wen-Fu Fu,a   Siu-Wai Lai,a   Yuan-Jun Houa  and  Yun-Ling Liua  

* Corresponding authors

a Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong SAR, China
E-mail: cmche@hku.hk
Fax: +852 2857 1586
Tel: +852 2859 2154

Abstract

Luminescent cyclometalated complex [Pt(L)py]+ (1) immobilised in Nafion film exhibits a solvatochromic shift in emission maximum from 530 to 650 nm upon immersion in ethanol but no effect is detected with aprotic organic solvents, whereas the emission of the [Pt(L)]+ luminophore anchored in silica materials shows a blue shift from ∼665 to 550 nm upon exposure to pentane vapour but no shift is observed for ethanol vapour.

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Article information

DOI
https://doi.org/10.1039/B210284F
Article type
Communication
Submitted
22 Oct 2002
Accepted
14 Nov 2002
First published
02 Dec 2002

Chem. Commun., 2003, 118-119

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Solvatochromic response imposed by environmental changes in matrix/chromophore entities: luminescent cyclometalated platinum(II) complex in Nafion and silica materials

C. Che, W. Fu, S. Lai, Y. Hou and Y. Liu, Chem. Commun., 2003, 118 DOI: 10.1039/B210284F

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