Frozen-solution magnetisation dynamics of hexanuclear oxime-based MnIII Single-Molecule Magnets

Ross Inglis; Jesper Bendix; Theis Brock-Nannestad; Høgni Weihe; Euan K. Brechin; Stergios Piligkos

doi:10.1039/C0SC00327A

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Frozen-solution magnetisation dynamics of hexanuclear oxime-based Mn^III Single-Molecule Magnets†

Ross Inglis,^a Jesper Bendix,^b Theis Brock-Nannestad,^b Høgni Weihe,^b Euan K. Brechin*^a and Stergios Piligkos*^b

Author affiliations

* Corresponding authors

^a School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: (+44)131-650-6453

^b Department of Chemistry, University of Copenhagen, Universitetsparken 5, Denmark
E-mail: piligkos@kiku.dk
Fax: (+45)3532-0133

Abstract

Frozen solution SQUID measurements of the hexanuclear Single-Molecule Magnets [Mn₆O₂(Et-sao)₆(EtOH)₆(Me₂benz)₂] (1) and [Mn₆O₂(Et-sao)₆(EtOH)₄(H₂O)₂(benz)₂] (2) allow the molecular and solid state contributions to the magnetic properties to be quantified.

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Article information

DOI: https://doi.org/10.1039/C0SC00327A
Article type: Edge Article
Submitted: 07 Jun 2010
Accepted: 03 Aug 2010
First published: 27 Aug 2010

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Chem. Sci., 2010,1, 631-636

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Frozen-solution magnetisation dynamics of hexanuclear oxime-based Mn^III Single-Molecule Magnets

R. Inglis, J. Bendix, T. Brock-Nannestad, H. Weihe, E. K. Brechin and S. Piligkos, Chem. Sci., 2010, 1, 631 DOI: 10.1039/C0SC00327A

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