Issue 3, 2011
From the journal:

Chemical Communications

Dihydrogenactivation by sulfido-bridged dinuclear Ru/Ge complexes: insight into the [NiFe] hydrogenase unready state†

Tsuyoshi Matsumoto,*a   Naohisa Itakura,a   Yukiko Nakayaa  and  Kazuyuki Tatsumi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan
E-mail: i45100a@nucc.cc.nagoya-u.ac.jp
Fax: +81 52-789-2943
Tel: +81 52-789-2474

Abstract

A S/SH bridged hetero-dinuclear Ru/Ge complex cation reacted with H2 to afford the μ-S/μ-H complex. The reaction was considerably slower compared to that of the μ-S/μ-OH complex. Thus, the μ-S/μ-SH and μ-S/μ-OH complexes might provide models for the unready and ready states, respectively, of [NiFe] hydrogenase.

Graphical abstract: Dihydrogen activation by sulfido-bridged dinuclear Ru/Ge complexes: insight into the [NiFe] hydrogenase unready state

  • This article is part of the themed collection: Hydrogen
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Article information

DOI
https://doi.org/10.1039/C0CC03391J
Article type
Communication
Submitted
21 Aug 2010
Accepted
22 Oct 2010
First published
11 Nov 2010

Chem. Commun., 2011,47, 1030-1032

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Dihydrogen activation by sulfido-bridged dinuclear Ru/Ge complexes: insight into the [NiFe] hydrogenase unready state

T. Matsumoto, N. Itakura, Y. Nakaya and K. Tatsumi, Chem. Commun., 2011, 47, 1030 DOI: 10.1039/C0CC03391J

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