Issue 6, 2011
From the journal:

Chemical Communications

Photocatalytic H2 evolution from neutral water with a molecular cobalt catalyst on a dye-sensitised TiO2 nanoparticle†‡

Fezile Lakadamyali§a  and  Erwin Reisner§*a  

* Corresponding authors

a School of Chemistry, The University of Manchester, Oxford Road, M13 9PL Manchester, UK
E-mail: er376@cam.ac.uk
Tel: +44 (0)1223 336323

Abstract

We report on a self-assembled system comprising of a molecular H2 production cobalt catalyst attached on a ruthenium dye-sensitised TiO2 nanoparticle. Visible light irradiation of the dispersed nanoparticles in the presence of the sacrificial electron donor triethanolamine produces H2 photocatalytically in pH neutral water and at room temperature.

Graphical abstract: Photocatalytic H2 evolution from neutral water with a molecular cobalt catalyst on a dye-sensitised TiO2 nanoparticle

  • This article is part of the themed collection: Hydrogen
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Article information

DOI
https://doi.org/10.1039/C0CC04658B
Article type
Communication
Submitted
28 Oct 2010
Accepted
06 Dec 2010
First published
07 Jan 2011

Chem. Commun., 2011,47, 1695-1697

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Photocatalytic H2 evolution from neutral water with a molecular cobalt catalyst on a dye-sensitised TiO2 nanoparticle

F. Lakadamyali and E. Reisner, Chem. Commun., 2011, 47, 1695 DOI: 10.1039/C0CC04658B

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