Little exchange at the liquid/solid interface: defect-mediated equilibration of physisorbed porphyrin monolayers

Michiel J. J. Coenen; Melissa Cremers; Duncan den Boer; Fieke J. van den Bruele; Tony Khoury; Maxine Sintic; Maxwell J. Crossley; Willem J. P. van Enckevort; Bas L. M. Hendriksen; Johannes A. A. W. Elemans; Sylvia Speller

doi:10.1039/C1CC12569A

Little exchange at the liquid/solid interface: defect-mediated equilibration of physisorbed porphyrin monolayers†‡

Michiel J. J. Coenen,^a Melissa Cremers,^a Duncan den Boer,^a Fieke J. van den Bruele,^a Tony Khoury,^b Maxine Sintic,^b Maxwell J. Crossley,^b Willem J. P. van Enckevort,^a Bas L. M. Hendriksen,^a Johannes A. A. W. Elemans*^a and Sylvia Speller^a

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^a Radboud University Nijmegen, Institute for Molecules and Materials, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands
E-mail: J.Elemans@science.ru.nl

^b School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia

Abstract

The transition from low to high density 2D surface structures of copper porphyrins at a liquid/solid interface requires specific defects at which nearly all exchange of physisorbed molecules with those dissolved in the supernatant occurs.

This article is part of the themed collection: Molecule-based surface chemistry

Chemical Communications

Little exchange at the liquid/solid interface: defect-mediated equilibration of physisorbed porphyrin monolayers†‡

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Little exchange at the liquid/solid interface: defect-mediated equilibration of physisorbed porphyrin monolayers

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