Issue 9, 2011
From the journal:

Organic & Biomolecular Chemistry

Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes†‡

Tsuyoshi Taniguchi,*a   Atsushi Idotaa  and  Hiroyuki Ishibashia  

* Corresponding authors

a School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa, Japan
E-mail: tsuyoshi@p.kanazawa-u.ac.jp
Fax: + 81-76-234-4439
Tel: + 81-76-234-4439

Abstract

Generation of sulfonyl radicals from sulfonylhydrazides has been achieved in the presence of a non-toxic iron catalyst and oxygen. The intermolecular addition of resultant sulfonyl radicals to alkenes affords β-hydroxysulfone compounds.

Graphical abstract: Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes

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Article information

DOI
https://doi.org/10.1039/C0OB01119C
Article type
Communication
Submitted
06 Dec 2010
Accepted
21 Feb 2011
First published
22 Feb 2011

Org. Biomol. Chem., 2011,9, 3151-3153

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Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes

T. Taniguchi, A. Idota and H. Ishibashi, Org. Biomol. Chem., 2011, 9, 3151 DOI: 10.1039/C0OB01119C

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