Issue 1, 2011
From the journal:

Chemical Science

Co–Gd phosphonate complexes as magnetic refrigerants†

Yan-Zhen Zheng,a   Marco Evangelistib  and  Richard E. P. Winpenny*ac  

* Corresponding authors

a School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK

b Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Departamento de Fisica de al Materia Condensada, Zaragoza, Spain

c The Photon Science Institute, The University of Manchester, Oxford Road, Manchester, UK
E-mail: richard.winpenny@manchester.ac.uk
Fax: (+44)161-275-4616

Abstract

Three 3d–4f phosphonate complexes, [CoII8GdIII8(μ3-OH)4(NO3)4(O3PtBu)8(O2CtBu)16], [CoII8GdIII4(O3PtBu)6(O2CtBu)16] and [CoII4GdIII6(O3PCH2Ph)6(O2CtBu)14(MeCN)2], have been synthesized and have structures that can be related to molecular grids. Magnetic studies show they have promise as low temperature magnetic refrigerants.

Graphical abstract: Co–Gd phosphonate complexes as magnetic refrigerants

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Article information

DOI
https://doi.org/10.1039/C0SC00371A
Article type
Edge Article
Submitted
14 Jul 2010
Accepted
31 Aug 2010
First published
24 Sep 2010

Chem. Sci., 2011,2, 99-102

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Co–Gd phosphonate complexes as magnetic refrigerants

Y. Zheng, M. Evangelisti and R. E. P. Winpenny, Chem. Sci., 2011, 2, 99 DOI: 10.1039/C0SC00371A

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