Issue 19, 2012

Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms

Abstract

Indium-mediated allylation of N-tert-butanesulfinyl ketimines afforded in high yields and diastereoselectivities homoallylic amine derivatives with the nitrogen atom bonded to a quaternary stereocenter.

Graphical abstract: Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms

  • This article is part of the themed collection: Chirality

Supplementary files

Article information

Article type
Communication
Submitted
30 Nov 2011
Accepted
11 Jan 2012
First published
12 Jan 2012

Chem. Commun., 2012,48, 2543-2545

Diastereoselective indium-mediated allylation of N-tert-butanesulfinyl ketimines: easy access to asymmetric quaternary stereocenters bearing nitrogen atoms

J. A. Sirvent, F. Foubelo and M. Yus, Chem. Commun., 2012, 48, 2543 DOI: 10.1039/C2CC17493F

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