Issue 34, 2012
From the journal:

Chemical Communications

Effects of cations and anions of ionic liquids on the production of 5-hydroxymethylfurfural from fructose†

Chunyan Shi,a   Yuling Zhao,b   Jiayu Xin,a   Jinquan Wang,a   Xingmei Lu,a   Xiangping Zhanga  and  Suojiang Zhang*a  

* Corresponding authors

a Beijing Key Laboratory of Ionic Liquids Clean Process, Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, PR China
E-mail: sjzhang@home.ipe.ac.cn
Fax: +86 82544875
Tel: +86 82544875

b Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Environmental Science, Henan Normal University, Xinxiang, Henan 453007, PR China

Abstract

Ionic liquids (ILs) with different cations and anions were used to study the effects on 5-hydroxymethylfurfural (HMF) preparation. It was found that both aggregations of cations and hydrogen bonds of anions with fructose played important roles. Molecular dynamics simulations were also performed to explain the experimental results.

Graphical abstract: Effects of cations and anions of ionic liquids on the production of 5-hydroxymethylfurfural from fructose

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Article information

DOI
https://doi.org/10.1039/C2CC30357D
Article type
Communication
Submitted
16 Jan 2012
Accepted
03 Mar 2012
First published
21 Mar 2012

Chem. Commun., 2012,48, 4103-4105

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Effects of cations and anions of ionic liquids on the production of 5-hydroxymethylfurfural from fructose

C. Shi, Y. Zhao, J. Xin, J. Wang, X. Lu, X. Zhang and S. Zhang, Chem. Commun., 2012, 48, 4103 DOI: 10.1039/C2CC30357D

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