Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand†‡
Abstract
The chiral iridium porphyrin [Ir((−)-D4-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards
- This article is part of the themed collection: Porphyrins & Phthalocyanines