Issue 44, 2012
From the journal:

Chemical Communications

Hydrogenation effects in metalloporphycenes: synthesis and redox behavior of Ni(ii)–tetra(n-propyl)dihydroporphycene†‡

Toru Okawara,a   Koichi Hashimoto,a   Masaaki Abe,*a   Hisashi Shimakoshia  and  Yoshio Hisaeda*ab  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: yhisatcm@mail.cstm.kyushu-u.ac.jp, mabe@mail.cstm.kyushu-u.ac.jp
Fax: +81-92-802-2827
Tel: +81-92-802-2826

b International Research Center for Molecular Systems (IRCMS), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17-tetrapropylporphycene 1 and its NiII complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.

Graphical abstract: Hydrogenation effects in metalloporphycenes: synthesis and redox behavior of Ni(ii)–tetra(n-propyl)dihydroporphycene

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Article information

DOI
https://doi.org/10.1039/C2CC30991B
Article type
Communication
Submitted
10 Feb 2012
Accepted
27 Mar 2012
First published
28 Mar 2012

Chem. Commun., 2012,48, 5413-5415

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Hydrogenation effects in metalloporphycenes: synthesis and redox behavior of Ni(II)–tetra(n-propyl)dihydroporphycene

T. Okawara, K. Hashimoto, M. Abe, H. Shimakoshi and Y. Hisaeda, Chem. Commun., 2012, 48, 5413 DOI: 10.1039/C2CC30991B

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