A stopped-flow method is used to study the effects of water and reactant acid anion TB− = tetrakis(pentafluorophenyl)borate on the homogeneous oxygen reduction catalyzed by the protonated tetraphenylporphyrin. Observed competitive inhibition of the catalyst is linked to the DFT free energy of extraction of O2, water, and TB− from the porphyrin complex.
A. Trojánek, J. Langmaier, S. Záliš and Z. Samec, Chem. Commun., 2012, 48, 4094 DOI: 10.1039/C2CC31082A
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
