Novel D–π–A structured Zn(ii)-porphyrin dyes containing a bis(3,3-dimethylfluorenyl)amine moiety for dye-sensitised solar cells

Abstract

A high solar-to-electricity conversion efficiency of 7.22% was achieved with a short circuit current (J_sc) of 15.30 mA cm⁻², an open circuit voltage (V_oc) of 669 mV and a fill factor (FF) of 0.71 for the 2Flu–ZnP–CN–COOH dye with a multi-functional co-adsorbent, under 100 mW cm⁻² AM 1.5 G simulated light.