Issue 43, 2012
From the journal:

Chemical Communications

Stereoselective amine-catalyzed carbohydrate chain elongation†‡

Benjamin Voigt,a   Ulf Schefflera  and  Rainer Mahrwald*a  

* Corresponding authors

a Institute of Chemistry, Humboldt-University, Brook-Taylor Str. 2, 12489 Berlin, Germany
E-mail: rainer.mahrwald@rz.hu-berlin.de
Fax: +49 (0)30 2093 5553

Abstract

Aldol additions of unprotected carbohydrates to 1.3-dicarbonyl compounds have been described. This transformation is based on a dual activation by tertiary amines and 2-hydroxypyridine.

Graphical abstract: Stereoselective amine-catalyzed carbohydrate chain elongation

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Article information

DOI
https://doi.org/10.1039/C2CC31541F
Article type
Communication
Submitted
29 Feb 2012
Accepted
26 Mar 2012
First published
27 Mar 2012

Chem. Commun., 2012,48, 5304-5306

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Stereoselective amine-catalyzed carbohydrate chain elongation

B. Voigt, U. Scheffler and R. Mahrwald, Chem. Commun., 2012, 48, 5304 DOI: 10.1039/C2CC31541F

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