Issue 56, 2012
From the journal:

Chemical Communications

Catalytic oxidation/C–H functionalization of N-arylpropiolamides by means of gold carbenoids: concise route to 3-acyloxindoles†

Deyun Qiana  and  Junliang Zhang*ab  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N, Zhongshan Road, Shanghai, 200062, P. R. China
E-mail: jlzhang@chem.ecnu.edu.cn
Fax: +86 21-6223-5039

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, P. R. China.

Abstract

An efficient catalytic C–H functionalization by means of gold carbenoids for the one-step synthesis of 3-acyloxindole derivatives has been developed. The reaction proceeds efficiently with extremely good substrate scope and significant opportunities for structural diversification.

Graphical abstract: Catalytic oxidation/C–H functionalization of N-arylpropiolamides by means of gold carbenoids: concise route to 3-acyloxindoles

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Article information

DOI
https://doi.org/10.1039/C2CC31972A
Article type
Communication
Submitted
18 Mar 2012
Accepted
24 May 2012
First published
24 May 2012

Chem. Commun., 2012,48, 7082-7084

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Catalytic oxidation/C–H functionalization of N-arylpropiolamides by means of gold carbenoids: concise route to 3-acyloxindoles

D. Qian and J. Zhang, Chem. Commun., 2012, 48, 7082 DOI: 10.1039/C2CC31972A

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