Issue 52, 2012
From the journal:

Chemical Communications

Chiral metal–organic frameworks with tunable open channels as single-site asymmetric cyclopropanation catalysts†‡

Joseph M. Falkowski,a   Sophie Liu,a   Cheng Wanga  and  Wenbin Lin*a  

* Corresponding authors

a Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599, USA
E-mail: wlin@unc.edu
Web: http://www.chem.unc.edu/people/faculty/linw/wlindex.html

Abstract

A pair of interpenetrated and non-interpenetrated chiral metal–organic frameworks with the same catalytic sites but different open channel sizes catalysed asymmetric cyclopropanation of substituted terminal alkenes with excellent diastereoselectivities (up to 9.6) and enantioselectivities (up to >99%).

Graphical abstract: Chiral metal–organic frameworks with tunable open channels as single-site asymmetric cyclopropanation catalysts

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC32232C
Article type
Communication
Submitted
05 Jan 2012
Accepted
08 May 2012
First published
08 May 2012

Chem. Commun., 2012,48, 6508-6510

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Chiral metal–organic frameworks with tunable open channels as single-site asymmetric cyclopropanation catalysts

J. M. Falkowski, S. Liu, C. Wang and W. Lin, Chem. Commun., 2012, 48, 6508 DOI: 10.1039/C2CC32232C

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