Issue 71, 2012
From the journal:

Chemical Communications

Conducting metallophthalocyanine 2D covalent organic frameworks: the role of central metals in controlling π-electronic functions†‡

Xuesong Ding,a   Xiao Feng,a   Akinori Saeki,b   Shu Seki,b   Atsushi Nagaia  and  Donglin Jiang*ac  

* Corresponding authors

a Department of Materials Molecular Science, Institute for Molecular Science, 5-1 Higashiyama, Myodaiji, Okazaki 444-8787, Japan
E-mail: jiang@ims.ac.jp
Fax: +81 564-59-5520
Tel: +81 564-59-5520

b Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

c Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), Japan

Abstract

Phthalocyanine covalent organic frameworks with different central metals are synthesized, and the AA-stacking structure of the 2D polymer sheets results in periodic phthalocyanine π-columns. The central metals control the π-electronic functions, including the improvement of light absorbance, the ease of carrier transport, and the photocurrent gain.

Graphical abstract: Conducting metallophthalocyanine 2D covalent organic frameworks: the role of central metals in controlling π-electronic functions

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Article information

DOI
https://doi.org/10.1039/C2CC33929C
Article type
Communication
Submitted
01 Jun 2012
Accepted
18 Jul 2012
First published
19 Jul 2012

Chem. Commun., 2012,48, 8952-8954

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Conducting metallophthalocyanine 2D covalent organic frameworks: the role of central metals in controlling π-electronic functions

X. Ding, X. Feng, A. Saeki, S. Seki, A. Nagai and D. Jiang, Chem. Commun., 2012, 48, 8952 DOI: 10.1039/C2CC33929C

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