Issue 79, 2013

Supramolecular photochirogenesis with functional amyloid superstructures

Abstract

Chiral variants of amyloid fibrils prepared by agitating acidified solutions of bovine insulin at 45 °C not only induced quasi-mirror-imaged circular dichroism spectra upon complexation with 2-anthracenecarboxylate but also gave anti-head-to-head-cyclodimers of the opposite absolute configurations upon photoirradiation.

Graphical abstract: Supramolecular photochirogenesis with functional amyloid superstructures

Supplementary files

Article information

Article type
Communication
Submitted
05 Jun 2013
Accepted
05 Jul 2013
First published
05 Jul 2013

Chem. Commun., 2013,49, 8916-8918

Supramolecular photochirogenesis with functional amyloid superstructures

M. Nishijima, H. Tanaka, C. Yang, G. Fukuhara, T. Mori, V. Babenko, W. Dzwolak and Y. Inoue, Chem. Commun., 2013, 49, 8916 DOI: 10.1039/C3CC44235G

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