Issue 1, 2013
From the journal:

CrystEngComm

Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs†

Scott Curtis,a   Olesya Ilkun,a   Amy Brown,a   Svitlana Silchenkoa  and  Nikolay Gerasimchuk*a  

* Corresponding authors

a Department of Chemistry, Missouri State University, Temple Hall 456, Springfield, MO, USA
E-mail: NNGerasimchuk@missouristate.edu
Fax: +1 4178365507
Tel: +1 4178365165

Abstract

Two new isomeric bis-cyanoximes were synthesized and characterized by a variety of spectroscopic methods including UV-visible, infrared, NMR, pKa measurements and X-ray analysis. These synthesized compounds represent the first non-chelating bis-cyanoximes that can function as building blocks for new MOF-like structures.

Graphical abstract: Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs

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Article information

DOI
https://doi.org/10.1039/C2CE26395E
Article type
Paper
Submitted
30 Aug 2012
Accepted
12 Oct 2012
First published
16 Oct 2012

CrystEngComm, 2013,15, 152-159

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Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs

S. Curtis, O. Ilkun, A. Brown, S. Silchenko and N. Gerasimchuk, CrystEngComm, 2013, 15, 152 DOI: 10.1039/C2CE26395E

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