Issue 45, 2013
From the journal:

Dalton Transactions

Photovoltaic properties of TiO2 loaded with glutathione-protected silver clusters

Nobuyuki Sakai,†a   Satoshi Nakamuraa  and  Tetsu Tatsuma*a  

* Corresponding authors

a Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan
E-mail: tatsuma@iis.u-tokyo.ac.jp
Fax: +81-3-5452-6338
Tel: +81-3-5452-6336

Abstract

Glutathione-protected Ag clusters (Ag15, Ag25 and Ag29) function as photosensitizers when they are adsorbed on TiO2 electrodes. [Co(bpy)3]2+ is the most appropriate electron donor among the cobalt complexes examined. Ag15 clusters yielded the highest internal quantum efficiency of 28% at 460 nm in the presence of [Co(bpy)3]2+ as a donor.

Graphical abstract: Photovoltaic properties of TiO2 loaded with glutathione-protected silver clusters

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Article information

DOI
https://doi.org/10.1039/C3DT51648B
Article type
Paper
Submitted
20 Jun 2013
Accepted
16 Aug 2013
First published
16 Aug 2013

Dalton Trans., 2013,42, 16162-16165

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Photovoltaic properties of TiO2 loaded with glutathione-protected silver clusters

N. Sakai, S. Nakamura and T. Tatsuma, Dalton Trans., 2013, 42, 16162 DOI: 10.1039/C3DT51648B

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