A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals

Pengfei Ai; Andreas A. Danopoulos; Pierre Braunstein; Kirill Yu. Monakhov

doi:10.1039/C3CC47370H

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A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d¹⁰ coinage metals†‡

Pengfei Ai,^a Andreas A. Danopoulos,*^ab Pierre Braunstein*^a and Kirill Yu. Monakhov^c

Author affiliations

* Corresponding authors

^a Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, 67081 Strasbourg Cedex, France
E-mail: danopoulos@unistra.fr, braunstein@unistra.fr

^b Institute for Advanced Study, USIAS, Université de Strasbourg, France

^c Institut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany

Abstract

A novel N,N′-diphosphanyl-imidazol-2-ylidene acts as a stable, hybrid PC_NHCP ligand for M₂ or linear M₃ (M = Cu, Ag, Au) arrays with metallophilic interactions.

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Article information

DOI: https://doi.org/10.1039/C3CC47370H
Article type: Communication
Submitted: 26 Sep 2013
Accepted: 22 Oct 2013
First published: 24 Oct 2013

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Chem. Commun., 2014,50, 103-105

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A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d¹⁰ coinage metals

P. Ai, A. A. Danopoulos, P. Braunstein and K. Yu. Monakhov, Chem. Commun., 2014, 50, 103 DOI: 10.1039/C3CC47370H

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