Mediator-less, direct electro-catalytic reduction of oxygen to water by bilirubin oxidase (Myrothecium sp.) was obtained on anthracene-modified, multi-walled carbon nanotubes. H2O2 was found to significantly and irreversibly affect the electro-catalytic activity of bilirubin oxidase, whereas similar electrodes comprised of laccase (Trametes versicolor) were reversibly inhibited.
R. D. Milton, F. Giroud, A. E. Thumser, S. D. Minteer and R. C. T. Slade, Chem. Commun., 2014, 50, 94 DOI: 10.1039/C3CC47689H
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