Issue 11, 2014
From the journal:

Chemical Communications

Stabilisation of μ-peroxido-bridged Fe(iii) intermediates with non-symmetric bidentate N-donor ligands†

József S. Pap,a   Apparao Draksharapu,b   Michel Giorgi,c   Wesley R. Browne,*b   József Kaizer*a  and  Gábor Speier*a  

* Corresponding authors

a Department of Chemistry, University of Pannonia, H-8200 Veszprém, Hungary
E-mail: kaizer@almos.vein.hu, speier@almos.uni-pannon.hu
Fax: +36 88 624 469
Tel: +36 88 624 720

b Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, Groningen, The Netherlands
E-mail: w.r.browne@rug.nl

c Aix-Marseille Université, FR1739, Spectropole, Campus St. Jérôme, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France

Abstract

The spectroscopic characterisation of the (μ-1,2-peroxido)diiron(III) species formed transiently upon reaction of [Fe(II)(NN)3]2+ complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.

Graphical abstract: Stabilisation of μ-peroxido-bridged Fe(iii) intermediates with non-symmetric bidentate N-donor ligands

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Article information

DOI
https://doi.org/10.1039/C3CC48196D
Article type
Communication
Submitted
25 Oct 2013
Accepted
25 Nov 2013
First published
26 Nov 2013

Chem. Commun., 2014,50, 1326-1329

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Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

J. S. Pap, A. Draksharapu, M. Giorgi, W. R. Browne, J. Kaizer and G. Speier, Chem. Commun., 2014, 50, 1326 DOI: 10.1039/C3CC48196D

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