Twistane is a classic hydrocarbon with fascinating stereochemical properties. Herein we describe a series of oligomers of twistane that converges on a chiral nanorod, which we term polytwistane. A member of this series, C2-symmetric tritwistane, has been synthesized for the first time.
M. Olbrich, P. Mayer and D. Trauner, Org. Biomol. Chem., 2014, 12, 108 DOI: 10.1039/C3OB42152J
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