Issue 7, 2014
From the journal:

Inorganic Chemistry Frontiers

Magnetocaloric effect and slow magnetic relaxation in two dense (3,12)-connected lanthanide complexes†

Song-De Han,a   Xiao-Hong Miao,a   Sui-Jun Liua  and  Xian-He Bu*a  

* Corresponding authors

a Department of Chemistry, TKL of Metal- and Molecule-Based Material Chemistry and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P.R. China
E-mail: buxh@nankai.edu.cn
Fax: +86-22-23502458

Abstract

Two (3,12)-connected complexes with distorted cubic [Ln4O4] (Ln = Gd (1), Dy (2)) building units were synthesized. The magnetic studies reveal that 1 features a large magnetocaloric effect with −ΔSmaxm = 51.29 J kg−1 K−1, and 2 displays slow magnetic relaxation behavior.

Graphical abstract: Magnetocaloric effect and slow magnetic relaxation in two dense (3,12)-connected lanthanide complexes

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Article information

DOI
https://doi.org/10.1039/C4QI00073K
Article type
Research Article
Submitted
20 May 2014
Accepted
23 Jun 2014
First published
24 Jun 2014

Inorg. Chem. Front., 2014,1, 549-552

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Magnetocaloric effect and slow magnetic relaxation in two dense (3,12)-connected lanthanide complexes

S. Han, X. Miao, S. Liu and X. Bu, Inorg. Chem. Front., 2014, 1, 549 DOI: 10.1039/C4QI00073K

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