Investigation of the light-induced electron-transfer-coupled spin transition in a cyanide-bridged [Co2Fe2] complex by X-ray diffraction and absorption measurements

Yoshihiro Sekine; Masayuki Nihei; Reiji Kumai; Hironori Nakao; Youichi Murakami; Hiroki Oshio

doi:10.1039/C4QI00074A

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Investigation of the light-induced electron-transfer-coupled spin transition in a cyanide-bridged [Co₂Fe₂] complex by X-ray diffraction and absorption measurements†

Yoshihiro Sekine,^a Masayuki Nihei,^a Reiji Kumai,^b Hironori Nakao,^b Youichi Murakami^b and Hiroki Oshio*^a

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* Corresponding authors

^a Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba 305-8571, Japan
E-mail: oshio@chem.tsukuba.ac.jp

^b Photon Factory and Condensed Matter Research Center, Institute of Materials Structures Sciences, High Energy Accelerator Research Organization, 1-1 Oho, Tsukuba 305-0801, Japan

Abstract

The light-induced electron-transfer-coupled spin transition (ETCST) behaviour in a cyanide-bridged [Co₂Fe₂] tetranuclear complex has been investigated in detail, using magnetic susceptibility measurements, single-crystal X-ray structural analyses and X-ray absorption spectroscopy.

$Graphical abstract: Investigation of the light-induced electron-transfer-coupled spin transition in a cyanide-bridged [Co2Fe2] complex by X-ray diffraction and absorption measurements$

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Article information

DOI: https://doi.org/10.1039/C4QI00074A
Article type: Research Article
Submitted: 21 May 2014
Accepted: 11 Jun 2014
First published: 13 Jun 2014

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Inorg. Chem. Front., 2014,1, 540-543

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Investigation of the light-induced electron-transfer-coupled spin transition in a cyanide-bridged [Co₂Fe₂] complex by X-ray diffraction and absorption measurements

Y. Sekine, M. Nihei, R. Kumai, H. Nakao, Y. Murakami and H. Oshio, Inorg. Chem. Front., 2014, 1, 540 DOI: 10.1039/C4QI00074A

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