Artificial photosynthesis on tree trunk derived alkaline tantalates with hierarchical anatomy: towards CO2 photo-fixation into CO and CH4

Abstract

Artificial photosynthesis, the photochemical fixation and recycling of CO₂ back to hydrocarbon fuels using sunlight and water, is both a significant challenge and an opportunity that, if realized, could have a revolutionary impact on our energy system. Herein, we demonstrate one of the first examples using biomass derived hierarchical porous photocatalysts for CO₂ photo-fixation into sustainable hydrocarbon fuels. A generic method is proposed to build a series of alkaline tantalates MTaO₃ (M = Li, Na, K) with hierarchical anatomy from macro- to nanoscales using activated carbonized tree trunks as templates. Artificial photosynthesis is carried out on MTaO₃ series using only artificial sunlight, water, and carbon dioxide as inputs to produce carbon monoxide and methane as the main outputs. The CO₂ photo-fixation performance can be enhanced by introducing a macropore network, which mainly enhances light transfer and accelerates gas diffusion. The research provides prototype models that integrate individual nanoscale components into higher level macroscopic artificial photosynthetic systems for better solar-to-fuel conversion efficiencies. This work would have potential significance for the ultimate construction of “artificial trees” and provide envisions creating “forests” of these CO₂-capturing artificial trees to remove carbon dioxide from the atmosphere and convert it into sustainable fuels.