A (POCOP)-supported palladium complex was used to catalyse the dehydrogenative borylation of terminal alkynes to form alkynylboronates. Competing hydrogenation reactions could be mitigated through the use of additives such as phosphines or elemental mercury.
C. J. Pell and O. V. Ozerov, Inorg. Chem. Front., 2015, 2, 720 DOI: 10.1039/C5QI00074B
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