An organic–inorganic hybrid supramolecular framework material based on a [P2W18O62]6− cluster and Yb & Na complexes of pyridine-2,6-dicarboxylic acid: a catalyst for selective oxidation of sulfides in water with H2O2

Pulikanti Guruprasad Reddy; Narsimha Mamidi; Chullikkattil P. Pradeep

doi:10.1039/C5CE02546J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

An organic–inorganic hybrid supramolecular framework material based on a [P₂W₁₈O₆₂]⁶⁻ cluster and Yb & Na complexes of pyridine-2,6-dicarboxylic acid: a catalyst for selective oxidation of sulfides in water with H₂O₂†

Pulikanti Guruprasad Reddy,^a Narsimha Mamidi

^a and Chullikkattil P. Pradeep*^a

Author affiliations

* Corresponding authors

^a School of Basic Sciences, Indian Institute of Technology Mandi, Mandi 175001, Himachal Pradesh, India
E-mail: pradeep@iitmandi.ac.in
Fax: +91 1905 267 009

Abstract

A rare-earth-containing polyoxometalate (RECP) hybrid, {(Yb (PDCH₂)₂(PDCH))·Na(H₂O)₂·(Na(PDCH)(H₂O)₂)}₂[P₂W₁₈O₆₂]·14H₂O (1), based on [P₂W₁₈O₆₂]⁶⁻ cluster anions and cationic Yb & Na complex units of pyridine-2,6-dicarboxylic acid (PDCH₂) has been synthesized under normal reaction conditions, which exhibited a supramolecular 3-D framework structure in the crystal lattice. Hybrid 1 acts as a green catalyst for the selective oxidation of sulfides in water with H₂O₂ as the reagent.

This article is part of the themed collection: 2016 New talent

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C5CE02546J
Article type: Communication
Submitted: 24 Dec 2015
Accepted: 04 Mar 2016
First published: 07 Mar 2016

Download Citation

CrystEngComm, 2016,18, 4272-4276

Permissions

Request permissions

An organic–inorganic hybrid supramolecular framework material based on a [P₂W₁₈O₆₂]⁶⁻ cluster and Yb & Na complexes of pyridine-2,6-dicarboxylic acid: a catalyst for selective oxidation of sulfides in water with H₂O₂

P. G. Reddy, N. Mamidi and C. P. Pradeep, CrystEngComm, 2016, 18, 4272 DOI: 10.1039/C5CE02546J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm