Copper(I) catalyzed C(sp2)–N bond formation: synthesis of pyrrolo[3,2-c]quinolinone derivatives

Zhiguo Zhang; Jingjing Qian; Guisheng Zhang; Nana Ma; Qingfeng Liu; Tongxin Liu; Kai Sun; Lei Shi

doi:10.1039/C5QO00417A

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Copper(i) catalyzed C(sp²)–N bond formation: synthesis of pyrrolo[3,2-c]quinolinone derivatives†

Zhiguo Zhang,*^a Jingjing Qian,^a Guisheng Zhang,*^a Nana Ma,^a Qingfeng Liu,^a Tongxin Liu,^a Kai Sun^ab and Lei Shi^a

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* Corresponding authors

^a Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, P. R. China
E-mail: zhangzg@htu.edu.cn, zgs6668@yahoo.com

^b College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, P. R. China

Abstract

An intramolecular copper-catalyzed direct C(sp²)–H activation/C(sp²)–N bond formation reaction has been developed for the synthesis of pyrrolo[3,2-c]quinolinone derivatives under an oxygen atmosphere.

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Article information

DOI: https://doi.org/10.1039/C5QO00417A
Article type: Research Article
Submitted: 09 Dec 2015
Accepted: 05 Jan 2016
First published: 11 Jan 2016

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Org. Chem. Front., 2016,3, 344-348

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Copper(I) catalyzed C(sp²)–N bond formation: synthesis of pyrrolo[3,2-c]quinolinone derivatives

Z. Zhang, J. Qian, G. Zhang, N. Ma, Q. Liu, T. Liu, K. Sun and L. Shi, Org. Chem. Front., 2016, 3, 344 DOI: 10.1039/C5QO00417A

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