A copper(I)-catalyzed one-pot [2 + 2 + 2] cascade annulation reaction of diaryliodoniums, nitriles, and aldehydes has been developed for the efficient synthesis of 2,4-substituted benzoxazine derivatives.
![Graphical abstract: Synthesis of benzo[1,3]oxazines via copper(i)-catalyzed cascade annulation of nitriles, aldehydes and diaryliodonium salts](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C6QO00012F&imageInfo.ImageIdentifier.Year=2016)
J. Sheng, X. Su, C. Cao and C. Chen, Org. Chem. Front., 2016, 3, 501 DOI: 10.1039/C6QO00012F
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