Issue 39, 2018
From the journal:

CrystEngComm

Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction†

Yiwen Zhang,ab   Kongzhao Su,a   Miao Hao,b   Lin Liu,*b   Zheng-Bo Hanb  and  Daqiang Yuan ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: ydq@firsm.ac.cn

b College of Chemistry, Liaoning University, Shenyang 110036, P. R. China
E-mail: ceshzb@lnu.edu.cn

Abstract

Two new three-dimensional metal–organic frameworks {[(CH3)2NH2]2[TM2(L)2]}n·x(solvent) (FJI-Y7, FJI = Fujian Institute, TM = Zn; FJI-Y8, TM = Cd) have been solvothermally prepared based on multifunctional pyridyl–tricarboxylate ligand 5-(5-carboxypyridin-3-yl)benzene-1,3-dicarboxylic acid (H3L). Single crystal X-ray analysis reveals that they possess non-interpenetrating binodal (4,4)-connected three-dimensional PtS-type networks with the Schläfli point symbol of {42·84}. Interestingly, both FJI-Y7 and FJI-Y8 can be used as highly efficient size-selective heterogeneous catalysts for the solvent-free cyanosilylation of acetaldehydes under mild conditions.

Graphical abstract: Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CE00694F
Article type
Paper
Submitted
29 Apr 2018
Accepted
24 Jul 2018
First published
24 Jul 2018

CrystEngComm, 2018,20, 6070-6076

Permissions

Request permissions

Two metal–organic frameworks based on pyridyl–tricarboxylate ligands as size-selective catalysts for solvent-free cyanosilylation reaction

Y. Zhang, K. Su, M. Hao, L. Liu, Z. Han and D. Yuan, CrystEngComm, 2018, 20, 6070 DOI: 10.1039/C8CE00694F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements