Issue 1, 2018

Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides

Abstract

A new protocol for achieving the phosphination of arenes, arenols and thiols has been disclosed. This chemistry, in which diaryl(((trifluoromethyl)sulfonyl)oxy)phosphines as a kind of electrophilic phosphination reagents are in situ generated from diarylphosphine oxides, provides an efficient and mild approach for the synthesis of aromatic organophosphorus compounds.

Graphical abstract: Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides

Supplementary files

Article information

Article type
Communication
Submitted
25 Oct 2017
Accepted
27 Nov 2017
First published
27 Nov 2017

Org. Biomol. Chem., 2018,16, 30-33

Metal-free electrophilic phosphination of electron-rich arenes, arenols and aromatic thiols with diarylphosphine oxides

T. Yuan, S. Huang, C. Cai and G. Lu, Org. Biomol. Chem., 2018, 16, 30 DOI: 10.1039/C7OB02620J

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