Three-dimensional ordered macroporous LaFe1−xMnxO3 with high stability for efficient NO oxidation and sulfur resistance

Shengjie Zuo; Ping Wang; Miao He; Jiasai Yao; Haocheng Li; Jing Xiong; Xiaohua Sun; Yuechang Wei; Zhenxing Li

doi:10.1039/D4CC01275E

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Three-dimensional ordered macroporous LaFe_1−xMn_xO₃ with high stability for efficient NO oxidation and sulfur resistance†

Shengjie Zuo,^a Ping Wang,^a Miao He,^a Jiasai Yao,^a Haocheng Li,^a Jing Xiong,^b Xiaohua Sun,*^a Yuechang Wei

*^b and Zhenxing Li

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum (Beijing), Beijing 102249, China
E-mail: lizx@cup.edu.cn, hua82@126.com

^b College of Science, China University of Petroleum (Beijing), Beijing 102249, China
E-mail: weiyc@cup.edu.cn

Abstract

NO_x is an air pollutant that affects human health. A series of perovskite catalysts with different ratios of lanthanum, iron, and manganese and a three-dimensional ordered microporous structure was prepared, and the strongest catalytic performance was obtained with the LaFe_0.1Mn_0.9O₃ catalyst. LaFe_0.1Mn_0.9O₃ possesses the greatest number of oxygen vacancies and reached 77% NO oxidation conversion at 250 °C, with the highest NO oxidation conversion of 99% at 318 °C. This work provides a promising non-precious metal catalyst for NO oxidation and soot combustion.

This article is part of the themed collection: 2024 Pioneering Investigators

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Article information

DOI: https://doi.org/10.1039/D4CC01275E
Article type: Communication
Submitted: 20 Mar 2024
Accepted: 08 Apr 2024
First published: 09 Apr 2024

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Chem. Commun., 2024,60, 5157-5160

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Three-dimensional ordered macroporous LaFe_1−xMn_xO₃ with high stability for efficient NO oxidation and sulfur resistance

S. Zuo, P. Wang, M. He, J. Yao, H. Li, J. Xiong, X. Sun, Y. Wei and Z. Li, Chem. Commun., 2024, 60, 5157 DOI: 10.1039/D4CC01275E

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