Upcycling of waste polyesters for the development of a circular economy

Abstract

The rapidly increasing production and widespread application of plastics have brought convenience to our lives, but they have consumed a huge amount of nonrenewable fossil energy, leading to additional CO2 emissions and generation of an enormous amount of plastic waste (also called white pollution). Chemical recycling and upcycling of waste plastic products (also called waste plastic refineries) into recycled monomers and/or valuable chemicals can decrease the dependence on fossil energy and/or reduce the emission of CO2, enabling the full utilization of carbon resources for the development of a circular economy. Polyesters, a vital class of plastics, are ideal feedstocks for chemical recycling due to the easily depolymerizable ester bonds compared to polyolefins. Among them, polyethylene terephthalate (PET) is the most widely used product, making its chemical recycling to a circular carbon resource a hot topic with significant concerns. In this feature article, recent progress in depolymerization of waste polyesters (PET and/or PET-containing materials) and the subsequent upgrading of depolymerized monomers (or intermediates) to valuable chemicals was reviewed and prospected. Newly reported technologies, such as thermal catalysis, photocatalysis, electrocatalysis, and biocatalysis, were discussed. The achievements, challenges, and potential of industrial applications of chemical recycling of polyesters were addressed.

Graphical abstract: Upcycling of waste polyesters for the development of a circular economy

Article information

Article type
Feature Article
Submitted
16 Sep 2024
Accepted
28 Oct 2024
First published
30 Oct 2024

Chem. Commun., 2024, Advance Article

Upcycling of waste polyesters for the development of a circular economy

H. Zhao, Y. Ye, Y. Zhang, L. Yang, W. Du, S. Wang and Z. Hou, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC04780J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements