Pd-catalyzed site-selective C–H functionalization/annulation of 2-aryl-1,3-dicarbonyls with Morita–Baylis–Hillman adducts has been accomplished to produce α-iso-/benzochromenyl acrylates. The cascade C–C and C–O bond formation, product selectivity, substrate scope and functional group tolerance are the important practical features.
S. Roy, S. Saha, H. Bhattacharyya and T. Punniyamurthy, Chem. Commun., 2025, 61, 9095 DOI: 10.1039/D5CC01800E
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