PVC/PAN-immobilized H2TiO3 adsorbent: a tailored titanium-based lithium-ion sieve for high-performance lithium recovery

Abstract

The increasing demand for lithium, driven by the rapid development of electric vehicles and energy storage systems, has created a pressing need for efficient and sustainable lithium recovery technologies. Conventional methods often face challenges related to selectivity, environmental impact, and scalability, necessitating the development of alternative materials. In this study, a polyvinyl chloride/polyacrylonitrile (PVC/PAN)-immobilized titanium-based lithium-ion sieve (HTO) was synthesized for lithium recovery from aqueous media, including geothermal brine. The objective was to obtain a selective, reusable, and mechanically stable adsorbent suitable for industrial-scale applications. The synthesized PVC/PAN-HTO composite was characterized by FT-IR, BET, XRD, and SEM techniques. Batch adsorption studies showed that the optimum lithium recovery occurred at pH 12, with efficiencies of 98.7% in model lithium solutions and 91.6% in geothermal water using a 4 g L⁻¹ adsorbent dosage. Adsorption kinetics followed a pseudo-second-order model, and the Langmuir isotherm provided the best fit, indicating monolayer adsorption with a maximum capacity of 5.79 mg g⁻¹. Thermodynamic analysis confirmed that the adsorption process is spontaneous and exothermic. Reusability tests demonstrated stable performance over three adsorption–desorption cycles, confirming the potential of PVC/PAN-HTO for practical lithium extraction applications.