Themed collection Reactive Capture of CO2
Reactive carbon capture using saline water: evaluation of prospective sources, processes, and products
This review synthesizes the state of development of saline water-based reactive carbon capture, assessing how sources, processes, and products impact viability.
Chem. Soc. Rev., 2025,54, 116-151
https://doi.org/10.1039/D4CS00701H
Electrochemical valorization of captured CO2: recent advances and future perspectives
This review highlights recent advancements and offers insights into the electrochemical conversion of captured CO2, focusing on capture medium, product control, system optimization, and the practical integration of CO2 capture and conversion.
Chem. Soc. Rev., 2025, Advance Article
https://doi.org/10.1039/D4CS00480A
Lignin-based porous carbon adsorbents for CO2 capture
This review covers the state-of-the-art in the production of lignin-based carbon adsorbents for CO2 capture, discussing lignin chemistry and properties, traditional synthesis approaches to emerging methods, and fundamentals for rational design.
Chem. Soc. Rev., 2025, Advance Article
https://doi.org/10.1039/D4CS00923A
Reactive capture and electrochemical conversion of CO2 with ionic liquids and deep eutectic solvents
Ionic liquids (ILs) and deep eutectic solvents (DESs) have tremendous potential for reactive capture of CO2, due to their highly properties, including a wide electrochemical stability window, low volatility, and high CO2 solubility.
Chem. Soc. Rev., 2024,53, 8563-8631
https://doi.org/10.1039/D4CS00390J
Reactive carbon capture using electrochemical reactors
Reactive carbon capture enables CO2 capture to be integrated with CO2 conversion using electrolysis to form valuable carbon products such as CO.
Chem. Soc. Rev., 2025, Advance Article
https://doi.org/10.1039/D4CS00834K
About this collection
Reactive Capture of CO2 (RCC) refers to a process integration where conversion of CO2 into a value-added product can be achieved directly from a sorbent which captures CO2. In some cases, it can be a solid sorbent working in concert with a catalyst or it can be a solution-phase sorbent which also serves as reaction medium for catalysis. In either scenario it has been estimated that RCC could provide 40% in energy savings relative to traditional CO2 capture and release since there is no need for thermal energy to be used to release CO2 before it is converted into fuel or chemical. It has been predicted that the products derived from RCC could be used to offset the costs of carbon capture when employed for industrial systems. Catalysis can be driven thermally or via an electrochemical system. It is well-known that CO2 sorbent mixtures are comprised of many equilibria, and therefore the substrate for RCC has the potential to be a variety of molecules and this leads to a potentially rich chemistry for CO2 conversion. As examples, RCC may have as substrate the CO2:sorbent adduct, or the substrate may be CO2 that is release from equilibria in the solid or solution phase sorbent.
Guest Edited by Louise Berben (UC Davis), Arnab Dutta (IIT Bombay), Deanna D’Alessandro (University of Sydney) and Jiwoong Lee (University of Copenhagen), this collection of reviews from some of the leading researchers in the field highlights exciting developments taking place across the globe in the field of RCC.