Themed collection Conference special issue: 6th EuChemS Conference on Green and Sustainable Chemistry

20 items
Open Access Review Article

The efficient synthesis of three-membered rings via photo- and electrochemical strategies

Three-membered rings, such as epoxides, aziridines, oxaziridines, cyclopropenes, vinyloxaziridines, and azirines, are recognized as crucial pharmacophores and building blocks in organic chemistry and drug discovery.

Graphical abstract: The efficient synthesis of three-membered rings via photo- and electrochemical strategies
Open Access Review Article

Csp2–H functionalization of phenols: an effective access route to valuable materials via Csp2–C bond formation

Simple phenols are crucial in the chemical value chain. Efforts aim to enhance their molecular complexity, with direct functionalization of Csp2–H as a key technique, facilitating economical and atomic construction of new Csp2–C bonds.

Graphical abstract: Csp2–H functionalization of phenols: an effective access route to valuable materials via Csp2–C bond formation
Open Access Critical Review

Procedural life cycle inventory of chemical products at laboratory and pilot scale: a compendium

Life Cycle Assessment (LCA) is widely acknowledged by academia and industry as a key tool for promoting environmental sustainability within the field of green chemistry.

Graphical abstract: Procedural life cycle inventory of chemical products at laboratory and pilot scale: a compendium
From the themed collection: 2024 Green Chemistry Reviews
Open Access Communication

Turning Pd-catalysed direct C–H arylation of thiophene derivatives into green : industrial wastewater as an effective reaction medium

The Pd-catalysed direct C–H arylation of thiophene derivatives, appealing for technological application, is performed under green conditions using low-purity grade industrial waste water as the sole reaction medium.

Graphical abstract: Turning Pd-catalysed direct C–H arylation of thiophene derivatives into green : industrial wastewater as an effective reaction medium
Communication

A miniaturized ozonolysis flow platform for expeditious sulfur mustard warfare simulant neutralization

DFT-guided development of a compact flow ozone platform for the neutralization of sulfur mustard simulants.

Graphical abstract: A miniaturized ozonolysis flow platform for expeditious sulfur mustard warfare simulant neutralization
Open Access Paper

Versatile NHC-based zinc and magnesium complexes for the synthesis and chemical recycling of aliphatic polyesters and polycarbonates

Applying the principles of green chemistry: synthesis of efficient catalysts, based on biocompatible metals, for the conversion of renewable monomers into sustainable polyesters and polycarbonates, and for the chemical recycling of polylactide.

Graphical abstract: Versatile NHC-based zinc and magnesium complexes for the synthesis and chemical recycling of aliphatic polyesters and polycarbonates
Open Access Paper

Bis-thiourea and macrocyclic polyamines as binary organocatalysts for the ROP of lactide

New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.

Graphical abstract: Bis-thiourea and macrocyclic polyamines as binary organocatalysts for the ROP of lactide
Open Access Paper

Efficient and selective extraction of oleanolic acid from grape pomace with dimethyl carbonate

A selective and environmentally friendly method for the extraction of oleanolic acid from grape pomace using bio-based and non-toxic dimethyl carbonate.

Graphical abstract: Efficient and selective extraction of oleanolic acid from grape pomace with dimethyl carbonate
Open Access Paper

Ligand coordination controlled by monomer binding: a hint from DFT for stereoselective lactide polymerization

Switching the preference in stereocontrolled rac-LA ROP.

Graphical abstract: Ligand coordination controlled by monomer binding: a hint from DFT for stereoselective lactide polymerization
Open Access Paper

A waste-minimized approach for the synthesis of iodinated organic borazines

We herein report a waste-minimized process for the synthesis of iodinated hexa-aryl borazines in different iodination patterns and amounts.

Graphical abstract: A waste-minimized approach for the synthesis of iodinated organic borazines
Open Access Paper

Introducing the use of a recyclable solid electrolyte for waste minimization in electrosynthesis: preparation of 2-aryl-benzoxazoles under flow conditions

The use of large amounts of a homogeneous electrolyte represents a major sustainability issue in electrosynthesis. Herein, we report the use of a solid and reusable electrolyte with excellent performance in the representative electrosynthesis of 2-arylbenzoxazoles.

Graphical abstract: Introducing the use of a recyclable solid electrolyte for waste minimization in electrosynthesis: preparation of 2-aryl-benzoxazoles under flow conditions
Open Access Paper

Microwave-assisted synthesis of ZnO structures for effective degradation of methylene blue dye under solar light illumination

A one-step microwave synthesis process was employed to generate highly effective ZnO photocatalysts for solar light-induced quick dye degradation.

Graphical abstract: Microwave-assisted synthesis of ZnO structures for effective degradation of methylene blue dye under solar light illumination
Open Access Paper

Facile synthesis of polycarbonates from biomass-based eugenol: catalyst optimization for selective copolymerization of CO2 and eugenol to achieve polycarbonates

A series of Co(III) and Cr(III)(salen) complexes in the presence of onium salts have been examined for the coupling of CO2 and biomass based eugenol epoxide for the selective production of polycarbonates in a partially sustainable process.

Graphical abstract: Facile synthesis of polycarbonates from biomass-based eugenol: catalyst optimization for selective copolymerization of CO2 and eugenol to achieve polycarbonates
Open Access Paper

Microwave assisted batch and continuous flow Suzuki–Miyaura reactions in GVL using a Pd/PiNe biowaste-derived heterogeneous catalyst

Aiming at the development of low-impact synthetic pathways, we herein report the simultaneous employment of different tools to improve the overall sustainability of the Suzuki–Miyaura (SM) cross-coupling with a circular economy approach.

Graphical abstract: Microwave assisted batch and continuous flow Suzuki–Miyaura reactions in GVL using a Pd/PiNe biowaste-derived heterogeneous catalyst
Open Access Paper

Carbon nanodots from orange peel waste as fluorescent probes for detecting nitrobenzene

An integrated approach combining thermal and electrochemical technologies for the valorization of agro-industrial waste. The resulting carbon dots (CDs) show fascinating optical properties, enabling their application as fluorescent chemical probes.

Graphical abstract: Carbon nanodots from orange peel waste as fluorescent probes for detecting nitrobenzene
Paper

Mechanically accelerated catalytic hydrogenation: correlating physical state, reaction rate, and interface area

This study thoroughly examines the role of mechanochemistry in organic synthesis by analysing the factors affecting the mechanochemical reduction process of unsaturated and oxidized compounds.

Graphical abstract: Mechanically accelerated catalytic hydrogenation: correlating physical state, reaction rate, and interface area
Open Access Paper

Cellulose modification for sustainable polymers: overcoming problems of solubility and processing

A flexible methodology to prepare water-soluble cellulose derivatives for easy processing is presented. The properties of the cellulose analogues are controllable, and the methodology enables further functionality to be added.

Graphical abstract: Cellulose modification for sustainable polymers: overcoming problems of solubility and processing
Open Access Paper

Bi-functional and mono-component organocatalysts for the ring-opening alternating co-polymerisation of anhydride and epoxide

The polyester synthesis from anhydrides and epoxides requires their strictly alternating incorporation achieved by a catalyst that is capable of mediating the reactivity of carboxylate and alcohol chain ends.

Graphical abstract: Bi-functional and mono-component organocatalysts for the ring-opening alternating co-polymerisation of anhydride and epoxide
Open Access Paper

N-Alkylation of aromatic amines with alcohols by using a commercially available Ru complex under mild conditions

An N-alkylation procedure has been developed under very mild conditions using a known commercially available Ru-based catalyst.

Graphical abstract: N-Alkylation of aromatic amines with alcohols by using a commercially available Ru complex under mild conditions
Open Access Paper

Catalytic synthesis of renewable phenol derivatives from biobased furanic derivatives

Here, we study a sequence Diels–Alder/aromatization reaction between biobased furanic derivatives and alkynes, paving the way to renewable phenols.

Graphical abstract: Catalytic synthesis of renewable phenol derivatives from biobased furanic derivatives
20 items

About this collection

In celebration of the 6th EuChemS Conference on Green and Sustainable Chemistry, which took place in Italy, September 2023, we are delighted to present a themed collection to celebrate research in this area. As a global society publisher, the RSC positions itself as a leading voice for the chemical sciences, which puts sustainability in the spotlight. We recognise the potential of the chemical sciences to provide innovative solutions to the most pressing challenges – and the importance of giving a platform to scientists whose discoveries catalyse global change. This collection celebrates both the vibrant and collaborative spirit of the conference, and the contribution green & sustainable chemistry makes to solving global challenges.

This series was Guest Edited by Professor Luigi Vaccaro (University of Perugia, Italy), Professor Arjan W. Kleij (ICIQ, Spain), Professor Ana Aguiar-Ricardo (NOVA University Lisbon, Portugal) and Professor Paolo Melchiorre (University of Bologna, Italy).

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