Themed collection Conference special issue: 6th EuChemS Conference on Green and Sustainable Chemistry


The efficient synthesis of three-membered rings via photo- and electrochemical strategies
Three-membered rings, such as epoxides, aziridines, oxaziridines, cyclopropenes, vinyloxaziridines, and azirines, are recognized as crucial pharmacophores and building blocks in organic chemistry and drug discovery.
Chem. Sci., 2024,15, 13576-13604
https://doi.org/10.1039/D4SC02512A

Csp2–H functionalization of phenols: an effective access route to valuable materials via Csp2–C bond formation
Simple phenols are crucial in the chemical value chain. Efforts aim to enhance their molecular complexity, with direct functionalization of Csp2–H as a key technique, facilitating economical and atomic construction of new Csp2–C bonds.
Chem. Sci., 2024,15, 3831-3871
https://doi.org/10.1039/D4SC00687A

Procedural life cycle inventory of chemical products at laboratory and pilot scale: a compendium
Life Cycle Assessment (LCA) is widely acknowledged by academia and industry as a key tool for promoting environmental sustainability within the field of green chemistry.
Green Chem., 2024,26, 9554-9568
https://doi.org/10.1039/D4GC01372G

Turning Pd-catalysed direct C–H arylation of thiophene derivatives into green : industrial wastewater as an effective reaction medium
The Pd-catalysed direct C–H arylation of thiophene derivatives, appealing for technological application, is performed under green conditions using low-purity grade industrial waste water as the sole reaction medium.
Green Chem., 2024,26, 7013-7018
https://doi.org/10.1039/D4GC01139B
A miniaturized ozonolysis flow platform for expeditious sulfur mustard warfare simulant neutralization
DFT-guided development of a compact flow ozone platform for the neutralization of sulfur mustard simulants.
Green Chem., 2024,26, 1281-1288
https://doi.org/10.1039/D3GC03470D

Versatile NHC-based zinc and magnesium complexes for the synthesis and chemical recycling of aliphatic polyesters and polycarbonates
Applying the principles of green chemistry: synthesis of efficient catalysts, based on biocompatible metals, for the conversion of renewable monomers into sustainable polyesters and polycarbonates, and for the chemical recycling of polylactide.
Catal. Sci. Technol., 2025,15, 822-835
https://doi.org/10.1039/D4CY01353K

Bis-thiourea and macrocyclic polyamines as binary organocatalysts for the ROP of lactide
New binary catalysts formed by a bis-thiourea and a series of flexible polyaza-macrocycles are revealed to be efficient catalysts for the ring opening polymerization (ROP) of L-lactide.
Catal. Sci. Technol., 2025,15, 71-80
https://doi.org/10.1039/D4CY00952E

Efficient and selective extraction of oleanolic acid from grape pomace with dimethyl carbonate
A selective and environmentally friendly method for the extraction of oleanolic acid from grape pomace using bio-based and non-toxic dimethyl carbonate.
Green Chem., 2024,26, 10177-10188
https://doi.org/10.1039/D4GC03624G

Ligand coordination controlled by monomer binding: a hint from DFT for stereoselective lactide polymerization
Switching the preference in stereocontrolled rac-LA ROP.
Catal. Sci. Technol., 2024,14, 5624-5633
https://doi.org/10.1039/D4CY00937A

A waste-minimized approach for the synthesis of iodinated organic borazines
We herein report a waste-minimized process for the synthesis of iodinated hexa-aryl borazines in different iodination patterns and amounts.
Green Chem., 2024,26, 7752-7758
https://doi.org/10.1039/D4GC00699B

Introducing the use of a recyclable solid electrolyte for waste minimization in electrosynthesis: preparation of 2-aryl-benzoxazoles under flow conditions
The use of large amounts of a homogeneous electrolyte represents a major sustainability issue in electrosynthesis. Herein, we report the use of a solid and reusable electrolyte with excellent performance in the representative electrosynthesis of 2-arylbenzoxazoles.
Green Chem., 2024,26, 6625-6633
https://doi.org/10.1039/D4GC00930D

Microwave-assisted synthesis of ZnO structures for effective degradation of methylene blue dye under solar light illumination
A one-step microwave synthesis process was employed to generate highly effective ZnO photocatalysts for solar light-induced quick dye degradation.
RSC Adv., 2024,14, 16293-16299
https://doi.org/10.1039/D4RA02451F

Facile synthesis of polycarbonates from biomass-based eugenol: catalyst optimization for selective copolymerization of CO2 and eugenol to achieve polycarbonates
A series of Co(III) and Cr(III)(salen) complexes in the presence of onium salts have been examined for the coupling of CO2 and biomass based eugenol epoxide for the selective production of polycarbonates in a partially sustainable process.
RSC Sustainability, 2024,2, 1431-1443
https://doi.org/10.1039/D4SU00145A

Microwave assisted batch and continuous flow Suzuki–Miyaura reactions in GVL using a Pd/PiNe biowaste-derived heterogeneous catalyst
Aiming at the development of low-impact synthetic pathways, we herein report the simultaneous employment of different tools to improve the overall sustainability of the Suzuki–Miyaura (SM) cross-coupling with a circular economy approach.
Green Chem., 2024,26, 4871-4879
https://doi.org/10.1039/D4GC00497C

Carbon nanodots from orange peel waste as fluorescent probes for detecting nitrobenzene
An integrated approach combining thermal and electrochemical technologies for the valorization of agro-industrial waste. The resulting carbon dots (CDs) show fascinating optical properties, enabling their application as fluorescent chemical probes.
RSC Sustainability, 2024,2, 933-942
https://doi.org/10.1039/D3SU00469D
Mechanically accelerated catalytic hydrogenation: correlating physical state, reaction rate, and interface area
This study thoroughly examines the role of mechanochemistry in organic synthesis by analysing the factors affecting the mechanochemical reduction process of unsaturated and oxidized compounds.
Green Chem., 2024,26, 1927-1934
https://doi.org/10.1039/D3GC03783E

Cellulose modification for sustainable polymers: overcoming problems of solubility and processing
A flexible methodology to prepare water-soluble cellulose derivatives for easy processing is presented. The properties of the cellulose analogues are controllable, and the methodology enables further functionality to be added.
RSC Sustainability, 2024,2, 369-376
https://doi.org/10.1039/D3SU00317E

Bi-functional and mono-component organocatalysts for the ring-opening alternating co-polymerisation of anhydride and epoxide
The polyester synthesis from anhydrides and epoxides requires their strictly alternating incorporation achieved by a catalyst that is capable of mediating the reactivity of carboxylate and alcohol chain ends.
Catal. Sci. Technol., 2023,13, 7011-7021
https://doi.org/10.1039/D3CY01424J

N-Alkylation of aromatic amines with alcohols by using a commercially available Ru complex under mild conditions
An N-alkylation procedure has been developed under very mild conditions using a known commercially available Ru-based catalyst.
RSC Adv., 2023,13, 34847-34851
https://doi.org/10.1039/D3RA06751C

Catalytic synthesis of renewable phenol derivatives from biobased furanic derivatives
Here, we study a sequence Diels–Alder/aromatization reaction between biobased furanic derivatives and alkynes, paving the way to renewable phenols.
RSC Adv., 2023,13, 30369-30377
https://doi.org/10.1039/D3RA06461A
About this collection
In celebration of the 6th EuChemS Conference on Green and Sustainable Chemistry, which took place in Italy, September 2023, we are delighted to present a themed collection to celebrate research in this area. As a global society publisher, the RSC positions itself as a leading voice for the chemical sciences, which puts sustainability in the spotlight. We recognise the potential of the chemical sciences to provide innovative solutions to the most pressing challenges – and the importance of giving a platform to scientists whose discoveries catalyse global change. This collection celebrates both the vibrant and collaborative spirit of the conference, and the contribution green & sustainable chemistry makes to solving global challenges.
This series was Guest Edited by Professor Luigi Vaccaro (University of Perugia, Italy), Professor Arjan W. Kleij (ICIQ, Spain), Professor Ana Aguiar-Ricardo (NOVA University Lisbon, Portugal) and Professor Paolo Melchiorre (University of Bologna, Italy).