Issue 1, 2021

Alternating polarity for enhanced electrochemical synthesis

Abstract

Synthetic electrochemistry has recently become an exciting technology for chemical synthesis. The majority of reported syntheses use either constant current or constant potential, however a few use non-linear profiles – mostly alternating polarity – to maintain efficiency throughout the process, such as controlling deposits on electrodes or ensuring even use of electrodes. However, even though parameters that are associated with such profiles, such as the frequency, can have a major impact on the reaction outcome, they are often not investigated. Herein, we report the crucial impact that the applied frequency of the alternating polarity has on the observed reaction rate of Cu(I)–NHC complex formation and demonstrate that this can be manipulated to give enhanced yield that is stable over extended reaction times.

Graphical abstract: Alternating polarity for enhanced electrochemical synthesis

Supplementary files

Article information

Article type
Paper
Submitted
08 אוק 2020
Accepted
21 אוק 2020
First published
29 אוק 2020
This article is Open Access
Creative Commons BY license

React. Chem. Eng., 2021,6, 147-151

Alternating polarity for enhanced electrochemical synthesis

C. Schotten, C. J. Taylor, R. A. Bourne, T. W. Chamberlain, B. N. Nguyen, N. Kapur and C. E. Willans, React. Chem. Eng., 2021, 6, 147 DOI: 10.1039/D0RE00399A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements