Issue 78, 2021

Weak base-promoted selective rearrangement of oxaziridines to amides via visible-light photoredox catalysis

Abstract

The selective rearrangement of oxaziridines to amides via a single electron transfer (SET) pathway is unexplored. In this study, we present a weak base-promoted selective rearrangement of oxaziridines to amides via visible-light photoredox catalysis. The developed method shows excellent functional group tolerance with a broad substrate scope and good to excellent yields. Furthermore, control experiments and density functional theory (DFT) calculations are performed to gain insight into the reactivity and selectivity.

Graphical abstract: Weak base-promoted selective rearrangement of oxaziridines to amides via visible-light photoredox catalysis

Supplementary files

Article information

Article type
Communication
Submitted
16 júl. 2021
Accepted
23 ágú. 2021
First published
23 ágú. 2021

Chem. Commun., 2021,57, 9995-9998

Weak base-promoted selective rearrangement of oxaziridines to amides via visible-light photoredox catalysis

J. Park, S. Park, G. S. Jang, R. H. Kim, J. Jung and S. K. Woo, Chem. Commun., 2021, 57, 9995 DOI: 10.1039/D1CC03855A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements