Issue 13, 2023

Recent advances in the heterogeneous photochemical synthesis of C–N bonds

Abstract

Over the few decades, photochemistry has received great attention and become a powerful tool in organic synthesis. Heterogeneous photocatalysts present complementary advantages in production, separation, catalyst recycling, and stability compared to the traditional homogeneous photocatalysts. In this review, we choose C–N bond formation as a typical coupling reaction and summarize the development of a heterogeneous catalytic system and its advantages. Titanium dioxide, semiconductor quantum dots, covalent organic frameworks, and carbon nitrides are discussed in detail as important heterogeneous photocatalysts. The combination and electron transfer pathway between heterogeneous catalysts and transition-metal catalysts are the focus of this review. These advances are not only limited to the C–N coupling, but also extend to other coupling reactions.

Graphical abstract: Recent advances in the heterogeneous photochemical synthesis of C–N bonds

Article information

Article type
Perspective
Submitted
21 mar. 2023
Accepted
23 maí 2023
First published
25 maí 2023

Green Chem., 2023,25, 5010-5023

Recent advances in the heterogeneous photochemical synthesis of C–N bonds

J. Wang, Y. Liu, X. Zong, A. Lei and Z. Sun, Green Chem., 2023, 25, 5010 DOI: 10.1039/D3GC00931A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements