Pd-Catalyzed double N-arylation of primary amines to synthesize phenoxazines and phenothiazines†
Heng
Li, 
a
Bingxin
Yuan
*a
and
a
Bingxin
Yuan
*a
and
Abstract
An efficient and versatile Pd-catalyzed tandem C–N bond formation between aryl halides and primary amines is developed. The transformation allows a one-pot synthesis of phenoxazine and phenothiazine derivatives with a broad range of substitution patterns from readily available precursors.
- This article is part of the themed collection: Celebrating excellence in research: women of organic chemistry
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