Issue 22, 2022

A review of biodegradable thermoplastic starches, their blends and composites: recent developments and opportunities for single-use plastic packaging alternatives

Abstract

Single-use plastic packaging has become an inevitable part of every aspect of human life. In fact, the increase in the consumption of petroleum-based single-use plastics has resulted in the accumulation of municipal solid wastes which are a leading source of plastic pollution worldwide. Biobased materials are a virtuous replacement for single-use petroleum-based packaging products, when recycling is difficult or not practical, to fulfil environmental and economic demands. Starch is an abundant biobased polymeric material that is sustainable and biodegradable. However, the inefficiency of starch in processability due to the existence of hydrogen bonding interactions and intermolecular forces impedes its applications. An effective solution is plasticization of starch in the presence of heat and shear, and is termed plasticized starch (PS). Although different sources may refer to plasticized starch (PS) as thermoplastic starch (TPS), the plasticization process does not make the starch a thermoplastic material until it is blended with toughened polymer, making the nomenclature counterintuitive. TPS is procured through the process of plasticization of starch with water and plasticizers followed by blending with tougher polymers/biopolymers. This could enhance the flexibility and processability of the blend materials, which are an effective replacement for petroleum-based single-use plastic packaging. In this review the main focus is on analysing the effect of multiple plasticizers and compatibility enhancers such as compatibilizers, coupling agents and essential oils in TPS blends, and starch-based composites’ preparation and their effective use in single-use packaging applications. Global production and market analysis of thermoplastic starches and their challenges in real-life packaging applications are also discussed.

Graphical abstract: A review of biodegradable thermoplastic starches, their blends and composites: recent developments and opportunities for single-use plastic packaging alternatives

Article information

Article type
Critical Review
Submitted
08 jún. 2022
Accepted
19 ágú. 2022
First published
03 nóv. 2022
This article is Open Access
Creative Commons BY license

Green Chem., 2022,24, 8606-8636

A review of biodegradable thermoplastic starches, their blends and composites: recent developments and opportunities for single-use plastic packaging alternatives

A. Surendren, A. K. Mohanty, Q. Liu and M. Misra, Green Chem., 2022, 24, 8606 DOI: 10.1039/D2GC02169B

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