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Novel water-dispersible donor–acceptor–donor π-conjugated bolaamphiphiles, having dibenzophenazine as the acceptor and heteroatom-bridged amphiphilic diarylamines as the donors, have been developed. The materials displayed a distinct photoluminescence color change in response to humidity in a poly(vinylalcohol) matrix.

Graphical abstract: Water-dispersible donor–acceptor–donor π-conjugated bolaamphiphiles enabling a humidity-responsive luminescence color change

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